用NMR 研究洋葱碳吸附水后的抗磁性

Diamagnetism of carbon onions probed by NMR of adsorbed water

  • 摘要: 对洋葱状碳缺陷位吸附水分子的1 H 化学位移进行测试,并比较块状水和石墨烯、氧化石墨烯和纳米金刚石吸附水的化学位移。纳米金刚石和氧化石墨烯绝缘体的1 H 共振位置与块状水接近,然而石墨烯和洋葱碳吸附水呈现明显的化学位偏移,这是由导电的石墨烯片层抗磁屏蔽效应所致。质子的化学位移和抗磁性之间存在显著的相关性。

     

    Abstract: We measured the 1 H chemical shift of water molecules adsorbed on defect sites of carbon onions and compared it with the shifts of bulk water and water adsorbed by chemically-derived graphene, graphene oxide and nanodiamond. The positions of 1H resonances for insulator nanodiamond and graphene oxide are close to that of bulk water, while water molecules adsorbed by graphene, and particularly by carbon onions, reveal a significant deviation in chemical shift from that of bulk water, which can be attributed to the diamagnetic screening effect of the conducting graphene layers. This conclusion is supported by a pronounced correlation established in our experiments between the proton chemical shifts and diamagnetic contribution to the magnetic susceptibility.

     

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